Isospecific Polymerization of Olefins: With Heterogeneous Ziegler-Natta Catalysts

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Ziegler-Natta catalysis: Forever young. MRS Bulletin , 38 03 , Ad Cohen, Geoffrey W. Coates, Moshe Kol. The potential of spectroscopic methods applied to heterogeneous catalysts for olefinpolymerization.

Heterogeneous and Homogeneous Ziegler-Natta Catalysts

The potential of spectroscopic methods applied to heterogeneous catalysts for olefin polymerization. Zirconium and hafnium Salalen complexes in isospecific polymerisation of propylene. Dalton Transactions , 42 25 , Carboranylimine-complexed titanium IV organometallics: An investigation of synthesis, structure and catalytic polymerization. Sameera, Feliu Maseras. Propylene polymerization over MgCl2-supported TiCl4 catalysts bearing different amounts of a diether internal electron donor: Extrapolation to the role of internal electron donor on active site.

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Heterogeneous and Homogeneous Ziegler-Natta Catalysts - PDF Drive

European Journal of Inorganic Chemistry , 17 , Severn, Giovanni Talarico. Macromolecular Rapid Communications , 28 10 , Chemistry - A European Journal , 13 3 , Resconi, J. Chadwick, L. Joanna K.


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Day, Rebecca E. Baghurst, Robert R. Strevens, Mark E. Light, Michael B. Hursthouse, Bruno F. Stengel, Ian A. Fallis, Simon Aldridge. New Journal of Chemistry , 31 1 , New J. Christopher E. Anson, Lukasz Ponikiewski, Alexander Rothenberger. Busico, R. Cipullo, R. Pellecchia, S. Ronca, G. Roviello, G. Design of stereoselective Ziegler-Natta propene polymerization catalysts.

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Group 4 metallocene polymerisation catalysts: quantification of ring substituent steric effects. Padmanabhan Sudhakar, Govindarajan Sundararajan. Macromolecular Rapid Communications , 26 23 , Chemistry - A European Journal , 11 21 , Macromolecular Chemistry and Physics , 18 , Jason B. Bulletin of the Chemical Society of Japan , 78 1 , ChemInform , 35 26 DOI: Pair your accounts. Your Mendeley pairing has expired. Please reconnect. Hint Swipe to navigate through the chapters of this book Close hint.

Abstract Kinetic investigations of olefin polymerization with Ziegler—Natta ZN catalysts provide information for understanding the mechanism of these reactions and are also necessary for development of industrial productions of polyolefins. In this chapter, the main kinetic features of olefin polymerization with heterogeneous ZN catalysts are considered as well as problems such as a deviation from the linear dependence of the rate of polymerization on monomer concentration, the hydrogen effect in ethene and propene polymerizations, and the comonomer effect, the natures of which are not yet completely clear and are discussed in the literature.

For analysis of the kinetics and mechanism of olefin polymerization, data on the number of active centers and propagation rate constants are important.

zeigler natta catalyst

The main methods for determination of these kinetic parameters are discussed in this chapter. Data on the number of active centers in ZN catalysts of different composition are presented. On the base of these kinetic data, the hydrogen effect and the heterogeneity of active centers at propylene polymerization over ZN catalysts are analyzed.

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